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Chemiluminescence imaging has been applied to a parametric investigation of diesel autoignition. Time-resolved images of the natural light emission were made in an optically accessible DI diesel engine of the heavy-duty size class using an intensified CCD video camera. Measurements were obtained at a base operating condition, corresponding to a motored TDC temperature and density of 992 K and 16.6 kg/m3, and for TDC temperatures and densities above and below these values. Data were taken with a 42.5 cetane number blend of the diesel reference fuels for all conditions, and measurements were also made with no. 2 diesel fuel (D2) at the base condition. For each condition, temporal sequences of images were acquired from the time of first detectable chemiluminescence up through fully sooting combustion, and the images were analyzed to obtain quantitative measurements of the average emission intensity.

An investigation has been conducted to determine the relative magnitude of the various factors that cause changes in combustion phasing (or required intake temperature) with changes in fueling rate in HCCI engines. These factors include: fuel autoignition chemistry and thermodynamic properties (referred to as fuel chemistry), combustion duration, wall temperatures, residuals, and heat/cooling during induction. Based on the insight gained from these results, the potential of fuel stratification to control combustion phasing was also investigated. The experiments were conducted in a single-cylinder HCCI engine at 1200 rpm using a GDI-type fuel injector. Engine operation was altered in a series of steps to suppress each of the factors affecting combustion phasing with changes in fueling rate, leaving only the effect of fuel chemistry.

To gain a better understanding of how the onset of incomplete bulk-gas reactions changes with engine speed and fuel-type, a parametric study of HCCI combustion and emissions has been conducted. The experimental part of the study was performed at naturally aspirated conditions and included fueling sweeps at four engine speeds (600, 1200, 1800 and 2400 rpm) for research grade gasoline, pure iso-octane and two mixtures of the primary reference fuels (i.e. n-heptane and iso-octane) with octane numbers of 80 and 60. Additionally, single-zone CHEMKIN computations with a detailed mechanism for iso-octane were conducted. The results show that there is a strong coupling between the ignition quality of the fuel and the required intake temperature to phase the combustion at TDC. There is also a direct influence of intake temperature on the completeness of combustion. This is the case because the CO-to-CO2 reactions are highly sensitive to the peak combustion temperatures.

We have developed a methodology for predicting combustion and emissions in a Homogeneous Charge Compression Ignition (HCCI) Engine. This methodology combines a detailed fluid mechanics code with a detailed chemical kinetics code. Instead of directly linking the two codes, which would require an extremely long computational time, the methodology consists of first running the fluid mechanics code to obtain temperature profiles as a function of time. These temperature profiles are then used as input to a multi-zone chemical kinetics code. The advantage of this procedure is that a small number of zones (10) is enough to obtain accurate results. This procedure achieves the benefits of linking the fluid mechanics and the chemical kinetics codes with a great reduction in the computational effort, to a level that can be handled with current computers.

The combustion process in diesel engines deposits soot on the in-cylinder surfaces. Previous works have suggested that these soot deposits eventually break off during cylinder blow-down and the exhaust stroke and contribute significantly to exhaust soot emissions. In order to better understand this potential pathway to soot emissions, the authors recently investigated combusting fuel-jet/wall interactions in a diesel engine. This work, published as a companion paper, showed how soot escaped from the combusting fuel jet and was brought in close proximity to the wall so that it could become a deposit. The current study extends this earlier work with laser-extinction measurements of the soot-deposition rate in the same single-cylinder, heavy-duty DI diesel engine. Measurements were made by passing the beam of a CW-diode laser through a window in the piston bowl rim that was in-line with one of the fuel jets.

Two fundamental aspects of HCCI engine combustion have been investigated using a single-zone model with time-varying compression and the full chemical-kinetic mechanisms for iso-octane, a representative liquid-phase fuel. This approach allows effects of the kinetics and thermodynamics to be isolated and evaluated in a well-characterized manner, providing an understanding of the selected fundamental processes. The computations were made using the CHEMKIN-III kinetic-rate code for an 1800 rpm operating condition. The study consists of two parts. First, low-load HCCI operation was investigated to determine the role of bulk-gas reactions as a source for HC and CO emissions. The computations show that as fueling is reduced to equivalence ratios of 0.15 and lower (very light load and idle), the bulk-gas reactions do not go to completion, leading to inefficient combustion and high emissions of HC and CO.

Homogeneous Charge Compression Ignition (HCCI) engines can have efficiencies as high as compression-ignition, direct-injection (CIDI) engines (an advanced version of the commonly known diesel engine), while producing ultra-low emissions of oxides of nitrogen (NOx) and particulate matter (PM). HCCI engines can operate on gasoline, diesel fuel, and most alternative fuels. While HCCI has been demonstrated and known for quite some time, only the recent advent of electronic sensors and controls has made HCCI engines a potential practical reality. This paper provides a comprehensive overview of the current state-of-the-art in HCCI technology, estimates the potential benefits HCCI engines could bring to U.S. transportation vehicles, and lists the R&D barriers that need to be overcome before HCCI engines might be considered for commercial application.

To better understand the factors affecting soot formation in diesel engines, in-cylinder soot and diffusion flame lift-off were measured in a heavy-duty, direct-injection diesel engine. Measurements were obtained at two operating conditions using two commercial diesel fuels and a range of oxygenated paraffinic fuel blends. A line-of-sight laser extinction diagnostic was improved and employed to measure the relative soot concentration within the jet (“jet-soot”) and the rates of soot-wall deposition on the piston bowl-rim. An OH chemiluminescence imaging technique was developed to determine the location of the diffusion flame and to measure the lift-off lengths of the diffusion flame to estimate the amount of oxygen entrainment in the diesel jets. Both the jet-soot and the rate of soot-wall deposition were found to decrease with increasing fuel oxygen-to-carbon ratio (O/C) over a wide range of O/C.

A combined experimental and modeling study has been conducted to investigate the sources of CO and HC emissions (and the associated combustion inefficiencies) at low-loads. Engine performance and emissions were evaluated as fueling was reduced from knocking conditions to very low loads (ϕ = 0.28 - 0.04) for a variety of operating conditions, including: various intake temperatures, engine speeds, compression ratios, and a comparison of fully premixed and GDI (gasoline-type direct injection) fueling. The experiments were conducted in a single-cylinder engine (0.98 liters) using iso-octane as the fuel. Comparative computations were made using a single-zone model with the full chemistry mechanisms for iso-octane, to determine the expected behavior of the bulk-gases for the limiting case of no heat transfer, crevices, or charge inhomogeneities.

The combustion behavior of conventional gasoline has been numerically investigated by means of detailed chemical-kinetic modeling simulations, with particular emphasis on analyzing the chemistry of the intermediate temperature heat release (ITHR). Previous experimental work on highly boosted (up to 325 kPa absolute) HCCI combustion of gasoline (SAE 2020-01-1086) showed a steady increase in the charge temperature up to the point of hot ignition, even for conditions where the ignition point was retarded well after top dead center (TDC). Thus, sufficient energy was being released by early pre-ignition reactions resulting in temperature rise during the early part of the expansion stroke This behavior is associated with a slow pre-ignition heat release (ITHR), which is critical to keep the engine from misfiring at the very late combustion phasings required to prevent knock at high-load boosted conditions.

The objective of this investigation is to verify and characterize the influence of fuel volatility on maximum liquid-phase fuel penetration for a variety of actual Diesel fuels under realistic Diesel engine operating conditions. To do so, liquid-phase fuel penetration was measured for a total of eight Diesel fuels using laser elastic-scatter imaging. The experiments were carried out in an optically accessible Diesel engine of the “heavy-duty” size class at a representative medium speed (1200 rpm) operating condition. In addition to liquid-phase fuel penetration, ignition delay was assessed for each fuel based on pressure-derived apparent heat release rate and needle lift data. For all fuels examined, it was observed that initially the liquid fuel penetrates almost linearly with increasing crank angle until reaching a maximum characteristic length. Beyond this characteristic length, the fuel is entirely vapor phase and not just smaller fuel droplets.

This work explores the potential of partial fuel stratification to smooth HCCI heat-release rates at high load. A combination of engine experiments and multi-zone chemical-kinetics modeling was used for this. The term “partial” is introduced to emphasize that care is taken to supply fuel to all parts of the in-cylinder charge, which is essential for reaching high power output. It was found that partial fuel stratification offers good potential to achieve a staged combustion event with reduced pressure-rise rates. Therefore, partial fuel stratification has the potential to increase the high-load limits for HCCI/SCCI operation. However, for the technique to be effective the crank-angle phasing of the “hot” ignition has to be sensitive to the local ϕ. Sufficient sensitivity was observed only for fuel blends that exhibit low-temperature heat release (like diesel fuel).

The effects of ambient gas thermodynamic state and fuel composition on the autoignition of natural gas under direct-injection diesel conditions were studied experimentally in a constant-volume combustion vessel and computationally using a detailed chemical kinetic model. Natural gas compositions representative of variations observed across the U.S. were considered. These results extend previous observations to more realistic natural gas compositions and a wider range of thermodynamic states that include the top-dead-center conditions in the natural gas version of the 6V-92 engine being developed by Detroit Diesel Corporation. At temperatures less than 1200 K, the experiments demonstrated that the ignition delay of natural gas under diesel conditions has a dependence on temperature that is Arrhenius in character and a dependence on pressure that is close to first order.

A combination of optical imaging diagnostics has been applied to the fuel jet of a direct-injection diesel engine to study the ignition and early soot formation processes. Measurements were made in an optically accessible direct-injection diesel engine of the “heavy-duty” size class at a representative medium speed (1200 rpm) operating condition. Two fuels were used, a 42.5 cetane number mixture of the diesel reference fuels and a new low-sooting fuel (needed to reduce optical attenuation at later crank angles) that closely matches both the cetane number and boiling point of the reference fuel mixture. The combustion and soot formation processes are found to be almost identical for both fuels. Ignition and early combustion were studied by imaging the natural chemiluminescence using a calibrated intensified video camera. The early soot development was investigated via luminosity imaging and simultaneous planar imaging of laser-induced incandescence (LII) and elastic scattering.

A parametric study of the liquid-phase fuel penetration of evaporating Diesel fuel jets has been conducted in a direct-injection Diesel engine using laser elastic-scatter imaging. The experiments were conducted in an optically accessible Diesel engine of the “heavy-duty” size class at a representative medium speed (1200 rpm) operating condition. The density and temperature at TDC were varied systematically by adjusting the intake temperature and pressure. At all operating conditions the measurements show that initially the liquid fuel penetrates almost linearly with increasing crank angle until reaching a maximum length. Then, the liquid-fuel penetration length remains fairly constant although fuel injection continues. At a TDC density of 16.6 kg/m3 and a temperature of about 1000 K the maximum penetration length is approximately 23 mm. However, it varies significantly as TDC conditions are changed, with the liquid-length being less at higher temperatures and at higher densities.

Autoignition of the five distinct isomers of hexane is studied experimentally under motored engine conditions and computationally using a detailed chemical kinetic reaction mechanism. Computed and experimental results are compared and used to help understand the chemical factors leading to engine knock in spark-ignited engines and the molecular structure factors contributing to octane rating for hydrocarbon fuels. The kinetic model reproduces observed variations in critical compression ratio with fuel structure, and it also provides intermediate and final product species concentrations in much better agreement with observed results than has been possible previously. In addition, the computed results provide insights into the kinetic origins of fuel octane sensitivity.

Combustion phasing is one important issue that must be addressed for HCCI operation. The intake temperature can be adjusted to achieve ignition at the desired crank angle. However, heat-transfer during induction will make the effective intake temperature different from the temperature measured in the runner. Also, depending on the engine speed and port configuration, dynamic flow effects cause various degrees of charge heating. Additionally, residuals from the previous cycle can have significant influence on the charge temperature at the beginning of the compression stroke. Finally, direct injection of fuel will influence the charge temperature since heat is needed for vaporization. This study investigates these effects in a systematic manner with a combination of experiment and cycle simulation using WAVE from Ricardo.

We have conducted a detailed numerical analysis of HCCI engine operation at low loads to investigate the sources of HC and CO emissions and the associated combustion inefficiencies. Engine performance and emissions are evaluated as fueling is reduced from typical HCCI conditions, with an equivalence ratio ϕ = 0.26 to very low loads (ϕ = 0.04). Calculations are conducted using a segregated multi-zone methodology and a detailed chemical kinetic mechanism for iso-octane with 859 chemical species. The computational results agree very well with recent experimental results. Pressure traces, heat release rates, burn duration, combustion efficiency and emissions of hydrocarbon, oxygenated hydrocarbon, and carbon monoxide are generally well predicted for the whole range of equivalence ratios. The computational model also shows where the pollutants originate within the combustion chamber, thereby explaining the changes in the HC and CO emissions as a function of equivalence ratio.

Gasoline consists of many different classes of hydrocarbons, such as paraffins, olefins, aromatics, and cycloalkanes. In this study, a surrogate gasoline reaction mechanism is developed, and it has one representative fuel constituent from each of these classes. These selected constituents are iso-octane, n-heptane, 1-pentene, toluene, and methyl-cyclohexane. The mechanism was developed in a step-wise fashion, adding submechanisms to treat each fuel component. Reactions important for low temperature oxidation (<1000K) and cross-reactions among different fuels are incorporated into the mechanism. The mechanism consists of 1328 species and 5835 reactions. A single-zone engine model is used to evaluate how well the mechanism captures autoignition behavior for conditions corresponding to homogeneous charge compression ignition (HCCI) engine operation.

Thermal stratification has the potential to reduce pressure-rise rates and allow increased power output for HCCI engines. This paper systematically examines how the amount of thermal stratification of the core of the charge has to be adjusted to avoid excessive knock as the engine speed and fueling rate are increased. This is accomplished by a combination of multi-zone chemical-kinetics modeling and engine experiments, using iso-octane as the fuel. The experiments show that, for a low-residual engine configuration, the pressure traces are self-similar during changes to the engine speed when CA50 is maintained by adjusting the intake temperature. Consequently, the absolute pressure-rise rate measured as bar/ms increases proportionally with the engine speed. As a result, the knocking (ringing) intensity increases drastically with engine speed, unless counteracted by some means.